benzene on the basis of the three-electron bond 2.8, graphite
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The present work shows the inapplicability of the Pauli principle to chemical bond, and a new theoretical model of the chemical bond is proposed based on the Heisenberg uncertainty principle. See pp. 88 - 104 Review (135 pages, full version). Benzene on the Basis of the Three-Electron Bond. (The Pauli exclusion principle, Heisenberg's uncertainty principle and chemical bond). http://vixra.org/pdf/1710.0326v3.pdfBenzene on the basis of the three-electron bond:
Review (135 pages, full version). Benzene on the Basis of the Three-Electron Bond. (The Pauli exclusion principle, Heisenberg's uncertainty principle and chemical bond). http://vixra.org/pdf/1710.0326v3.pdf
1. Structure of the benzene molecule on the basis of the three-electron bond.
http://vixra.org/pdf/1606.0152v1.pdf
2. Experimental confirmation of the existence of the three-electron bond and theoretical basis ot its existence.
http://vixra.org/pdf/1606.0151v2.pdf
3. A short analysis of chemical bonds.
http://vixra.org/pdf/1606.0149v2.pdf
4. Supplement to the theoretical justification of existence of the three-electron bond.
http://vixra.org/pdf/1606.0150v2.pdf
5. Theory of three-electrone bond in the four works with brief comments.
http://vixra.org/pdf/1607.0022v2.pdf
6. REVIEW. Benzene on the basis of the three-electron bond. http://vixra.org/pdf/1612.0018v5.pdf
7. Quantum-mechanical aspects of the L. Pauling's resonance theory.
http://vixra.org/pdf/1702.0333v2.pdf
8. Quantum-mechanical analysis of the MO method and VB method from the position of PQS.
http://vixra.org/pdf/1704.0068v1.pdf
9. Review (135 pages, full version). Benzene on the Basis of the Three-Electron Bond. (The Pauli exclusion principle, Heisenberg's uncertainty principle and chemical bond). http://vixra.org/pdf/1710.0326v3.pdf
Bezverkhniy Volodymyr (viXra): http://vixra.org/author/bezverkhniy_volodymyr_dmytrovych
Bezverkhniy Volodymyr (Scribd):
https://www.scribd.com/user/289277020/Bezverkhniy-Volodymyr#
https://www.amazon.com/Volodymyr-Bezverkhniy/e/B01I41EHHS/ref=dp_byline_cont_ebooks_1
benzene on the basis of the three-electron bond, graphite.
From these equations we find:
c\u2013c benzene multiplicity (L = 1.397 A) = 1.658
c\u2013c graphite multiplicity (L = 1.42 A) = 1.538 \u2248 1.54
Ec\u2013c benzene (L = 1.397 A) = 534.0723 kj/mole
Ec\u2013c graphite (L = 1.42 A) = 503.3161 kj/mole.
The fact of the distance between the graphite layers being 3.35 A (the \u0421-\u0421 bond
length inside the layer making 1.42 A) may serve as an indirect confirmation of the
possibility of interaction of the electrons through the cycle in benzene. This causes a weak bond between the layers and, as a result, the ability of the layers to shift relative to each other. Since the distance between the central electrons in benzene is less and makes 2.420 A (in case of an interaction through the cycle), we should expect a stronger interaction.
https://www.scribd.com/user/289277020/Bezverkhniy-Volodymyr#
https://www.amazon.com/Volodymyr-Bezverkhniy/e/B01I41EHHS/ref=dp_byline_cont_ebooks_1
benzene on the basis of the three-electron bond, graphite.
From these equations we find:
c\u2013c benzene multiplicity (L = 1.397 A) = 1.658
c\u2013c graphite multiplicity (L = 1.42 A) = 1.538 \u2248 1.54
Ec\u2013c benzene (L = 1.397 A) = 534.0723 kj/mole
Ec\u2013c graphite (L = 1.42 A) = 503.3161 kj/mole.
The fact of the distance between the graphite layers being 3.35 A (the \u0421-\u0421 bond
length inside the layer making 1.42 A) may serve as an indirect confirmation of the
possibility of interaction of the electrons through the cycle in benzene. This causes a weak bond between the layers and, as a result, the ability of the layers to shift relative to each other. Since the distance between the central electrons in benzene is less and makes 2.420 A (in case of an interaction through the cycle), we should expect a stronger interaction.
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