benzene on the basis of the three-electron bond 2.14, [18]

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benzene on the basis of the three-electron bond, [18]-annulene.

By the example of [18]-annulene it is possible to illustrate interaction through the cycle of central electrons of three-electron bonds. Interacting through the cycle, it shifts to the centre in the direction of inner atoms of hydrogen thus increasing electron density within the cycle and decreasing outside the cycle. And that\u2019s why outside protons (12 \u041d) will give signals in the area of weaker field (reduction of electron density), and inner (6 \u041d) will give signals in the area of stronger field (increase of electron density). Thus this is observed in reality [7]. It also should be noted that inner protons bracing central electrons strengthen interaction through the cycle, and so stabilize aromatic system. But interaction through the cycle is decisive.

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